Radical cyclization of epoxyketones via a 1,5-Bun 3Sn group or a 1,5-H atom transfer

1 January 1992

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 18,p. 1377-1378
https://doi.org/10.1039/c39920001377

Abstract

Radical cyclization of epoxyketones is initiated by Buⁿ ₃Sn radical addition to epoxyketones, followed by epoxide fragmentation, 1,5-H- or 1,5-Buⁿ ₃Sn transfer, and cyclization.

Keywords

EPOXIDE
ATOM
CYCLIZATION OF EPOXYKETONES
RADICAL CYCLIZATION
BUN3SN

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