Heterometallic CeIII???FeIII???salicylate networks: models for corrosion mitigation of steel surfaces by the ???Green??? inhibitor, Ce(salicylate)3
- 25 October 2002
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2820-2821
- https://doi.org/10.1039/b207722a
Abstract
The syntheses and structures of the novel Ce–Fe bimetallic complexes [{Fe(sal)2(bpy)}2Ce(NO3)(H2O)3]·EtOH and [{Fe(sal)2(bpy)}4Ce2(H2O)11][salH]2·EtOH·3H2O (salH2 = salicylic acid) suggest Fe3+–sal2− units and Ce–OC(R)O–Fe bridging contribute to the formation of corrosion inhibitive layers on steel surfaces exposed to [Ce(salH)3(H2O)].Keywords
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