Cascade complexation of pseudo-halide by dicopper cryptates: a linear Cu–NNN–Cu unit
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 15,p. 3227-3230
- https://doi.org/10.1039/dt9960003227
Abstract
An X-ray crystallographic structure determination of a µ-azido azacryptate has confirmed the existence of collinear Cu–NNN–Cu geometry, earlier cited as the origin of unusual spectroscopy in dicopper µ-azido cryptates; the isoelectronic µ-cyanato cryptate is also isostructural.Keywords
This publication has 13 references indexed in Scilit:
- Hydrolytically-sensitive hexaimino and hydrolytically-inert octaamino-cryptand hosts for dicopperJ. Chem. Soc., Dalton Trans., 1995
- Caged anions: perchlorate and perfluoroanion cryptatesJournal of the Chemical Society, Chemical Communications, 1995
- Dicopper cryptates with 1,1 and 1,3 bridging ligands: spectroscopic, magnetic and electrochemical propertiesJ. Chem. Soc., Dalton Trans., 1994
- Pyridinophane cryptand hosts with dicopper(I) or dicopper(II) preferencesInorganica Chimica Acta, 1993
- Design of anion receptors: ApplicationsPure and Applied Chemistry, 1993
- Cascade complexes of an octaaza cryptand: co-ordinated azide with linear M–NNN–M geometryJ. Chem. Soc., Dalton Trans., 1992
- Facile synthesis of a new family of cage moleculesTetrahedron Letters, 1988
- Polyaza macrobicyclic cryptands: synthesis, crystal structures of a cyclophane type macrobicyclic cryptand and of its dinuclear copper(I) cryptate, and anion binding featuresJournal of the Chemical Society, Chemical Communications, 1987
- Copper(II) hemocyanin modelsJournal of the American Chemical Society, 1981
- Bimetallic copper(I) and -(II) macrocyclic complexes as mimics for type 3 copper pairs in copper enzymesJournal of the American Chemical Society, 1979