Approaches to some carbohydrate-derived sultones
- 15 January 1981
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 59 (2) , 260-263
- https://doi.org/10.1139/v81-042
Abstract
Under some conditions deprotonation of various mixed disulfonate ester derivatives of carbohydrates leads to intramolecular displacement yielding a product in which a sultone is fused to the sugar ring. The procedure seems to work best when a mesylate and a benzenesulfonate are involved. Examples with both pyranose and furanose sugars are described.Keywords
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