On the reaction of methylmagnesium bromide with benzophenone: the effect of magnesium metal purity on kinetic data
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 6,p. 330-332
- https://doi.org/10.1039/c29700000330
Abstract
Previously reported complications in the interpretation of kinetic data of Grignard–ketone reactions due to by-product formation and dependence of rate constant on ketone concentrations have been eliminated by use of ultra-pure magnesium for the preparation of the Grignard reagent; however, a further previously unobserved complication involving a non first-order disappearance of ketone has been observed.Keywords
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