He-I photoelectron spectra of some d 0 transition metal compounds
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 70, 1895-1911
- https://doi.org/10.1039/f29747001895
Abstract
Photoelectron spectra excited in the gas phase with He-I radiation are reported for the tetroxides, RuO4 and OsO4, and for the oxychloride species VOCl3, CrO2Cl2 and MoO2Cl2. The X-ray photoelectron spectrum of OsO4 has also been measured. The nature of the metal-oxygen bonding in these molecules, as inferred from the spectrometric data, is discussed.Keywords
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