Scattering lengths and effective ranges for He-He and spin-polarized H-H and D-D scattering

Abstract
The modifications of effective-range theory, necessitated by the long-range nature of interatomic dispersion and relativistic retardation forces, are discussed. A numerical comparison is given of parameters describing 33He, 43He, and 44He scattering at very low energies calculated with several recently published interaction potentials. The effect of relativistic retardation on these parameters and on the calculated binding energies of the 44He dimer is shown. It is demonstrated that all of these quantities are extremely sensitive to the potential. Scattering lengths and effective ranges for the lowest triplet interactions of H-H and D-D are also reported.