Straightforward route to 2- and 3-formyl hex-1- and -2-enopyranosides and their highly stereoselective hetero Diels–Alder reaction with ethyl vinyl ether
- 1 January 1988
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 514-515
- https://doi.org/10.1039/c39880000514
Abstract
A straightforward route from D-glucose to conjugated enal and diene pyranoses through a dithiane-based methodology is disclosed; hetero Diels–Alder reaction of the enals with ethyl vinyl ether occurs with high stereoselectivity.Keywords
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