NEW SYNTHESES OF β-ALKOXY KETONES AND β-KETO ACETALS
- 5 January 1974
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 3 (1) , 15-16
- https://doi.org/10.1246/cl.1974.15
Abstract
It was found that trimethylsilyl enol ethers derived from aldehydes and ketones react smoothly with acetals or methyl orthoformate at −78°C in the presence of TiCl4, to give β-alkoxy ketones or β-keto acetals, respectively, in good yields.Keywords
This publication has 3 references indexed in Scilit:
- Reduction of Carbonyl Compounds with Various Hydrosilane-Rhodium(I) Complex CombinationsBulletin of the Chemical Society of Japan, 1972
- Chemistry of carbanions. XVIII. Preparation of trimethylsilyl enol ethersThe Journal of Organic Chemistry, 1969
- Isolation of ketone enolates as trialkylsilyl ethersJournal of the American Chemical Society, 1968