Steric inhibition of resonance studied by molecular photoelectron spectroscopy. Part 3.—Anilines, phenols and related compounds
- 1 January 1973
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 69, 521-531
- https://doi.org/10.1039/f29736900521
Abstract
Photoelectron spectroscopic data for amino- and oxy-benzenes are discussed in terms of a simple p-π interaction scheme. Steric hindrance is shown only to be important in ortho substituted NN-dialkylanilines and in 2,6-dimethylanisole. In the nitrogen series there is indication that the N atom is not planar.Keywords
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