The Heats of Dilution in Atactic Polymethyl Methacrylate Solutions
- 1 January 1967
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 40 (1) , 11-15
- https://doi.org/10.1246/bcsj.40.11
Abstract
In order to ascertain the dependence of the interaction parameter, χH, between the polymer and the solvent molecules on the polymer concentration, the heats of dilution in an atactic polymethyl methacrylate solution have been measured for the polymers with the degrees of polymerization of 3000 and 7800. It was found that the values of χH obtained are dependent on the concentration in all the solvents used, as in the solutions of polystyrene and polybutadiene reported as in previous papers. χH depends also on the molecular weight, this is in agreement with the suggestion by Huggins (J. Am. Chem. Soc., 86, 3535 (1964)).This publication has 4 references indexed in Scilit:
- The Heats of the Dilution of cis-Polybutadiene Solutions in Benzene and TolueneBulletin of the Chemical Society of Japan, 1966
- The Heats of Dilution of Atactic Polystyrene SolutionsBulletin of the Chemical Society of Japan, 1966
- A Revised Theory of High Polymer SolutionsJournal of the American Chemical Society, 1964
- Properties of dilute polymer solutions IIIIntrinsic viscosity/temperature relationships for conventional polymethyl methacrylatePolymer, 1962