Synthesis of a Novel Amphoteric Polyelectrolyte by Polymerization of 6‐Amino‐2,4‐hexadienoic Acid in Layer Perovskites
- 1 August 1981
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 20 (8) , 687
- https://doi.org/10.1002/anie.198106871
Abstract
The topochemically controlled polymerization of 6‐amino‐2,4‐hexadienoic acid in complexes with CdCl2, MnCl2 and FeCl2 is initiated by UV or 60Co‐γ‐radiation. Tacticity of the polymer, slight structural changes during transition from the monomer to polymer and control of reactivity by the type of ion in the matrix render the proposed course of reaction likely. The liberated amphoteric polyelectrolyte could be suitable as a polymeric complexing agent.Keywords
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