An enantio- and stereo-controlled synthesis ofL-erythro- andD-threo-C18-sphingosines via the anomalous version of the katsuki–sharpless asymmetric epoxidation reaction
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 820-821
- https://doi.org/10.1039/c39910000820
Abstract
A new enantiocontrolled synthesis of L-erythro- and D-threo-sphingosines has been established starting from (R,R)- and meso-1,2-divinylethylene glycols via the anomalous version of the Katsuki–Sharpless asymmetric epoxidation reaction as the key step.Keywords
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