Self-assembly of a bisporphyrin supramolecular cage induced by molecular recognition between complementary hydrogen bonding sites
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 243-245
- https://doi.org/10.1039/c39930000243
Abstract
Addition of an alkyl substituted triaminopyrimidine, TAP, to a solution of porphyrin 2 bearing two rigidly attached complementary hydrogen bonding moieties of the uracil type, leads to the self-assembly of a bisporphyrin supramolecular cage structure 1 from the syn rotamer and probably a zig-zag strand from the anti rotamer.Keywords
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