Crystal and molecular structure of NN-dimethyldiphenylphosphinamide

Abstract
The crystal and molecular structure of the title compound (I) has been determined by single-crystal X-ray diffraction. Crystals are orthorhombic, space group P212121, a= 7.670(4), b= 11.141(3), c= 15.644(5)Å, and Z= 4. The structure was solved from diffractometer data by the heavy-atom technique. Positional and anisotropic thermal parameters were refined by full-matrix least-squares methods to a final R factor of 6.5% for 1 005 observed reflections. The phosphorus, nitrogen, and two methyl carbon atoms are non-planar.

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