Novel amine-modified TiO2–SiO2 aerogel for the demanding epoxidation of substituted cyclohexenols

1 January 1999

journal article
research article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 2,p. 197-198
https://doi.org/10.1039/a808374f

Abstract

Amine additives provided high selectivity (up to 98%) in the epoxidation of sensitive alkyl-substituted cyclohexenols with a TiO₂–SiO₂ aerogel and Bu^tOOH; heterogenization of the catalyst system resulted in a new bifunctional catalyst.

Keywords

TIO2
SIO2
AEROGEL
ADDITIVES PROVIDED
AMINE MODIFIED
BIFUNCTIONAL CATALYST
SENSITIVE ALKYL
SYSTEM RESULTED
NOVEL AMINE

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