31P nuclear magnetic resonance study of conformers of trans-[MCl(CO)(PBu2 tR)2](M = Rh or Ir; R = Me, Et, or Prn)

1 January 1971

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications

No. 18,p. 1103-1104
https://doi.org/10.1039/c29710001103

Abstract

The low temperature ³¹P n.m.r. spectra of the complexes trans-[MCl(CO)(PRBu^t ₂)₂](M = Rh or Ir; R = Me, Et, or Prⁿ) show the presence of three rotamers with very different chemical shifts.

Keywords

NUCLEAR MAGNETIC RESONANCE