Determination of the vibration frequency of the high temperature species AuLi by means of matrix isolation spectroscopy
- 1 June 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (11) , 5105-5107
- https://doi.org/10.1063/1.433767
Abstract
The high temperature species AuLi has been studied by matrix isolation infrared spectroscopy, and its stretching force constant has been found to be (1.90±0.03) ×105 dyn/cm. Sufficiently high concentrations of this molecule were achieved by application of a double‐Knudsen cell arrangement, from which metallic gold and lithium could be evaporated at different temperatures.Keywords
This publication has 6 references indexed in Scilit:
- Mass spectrometric determination of the dissociation energies of the molecules CuLi, AgLi and AuLiJournal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1974
- Some Infrared Spectra of Matrix-Isolated Lithium FluorideThe Journal of Chemical Physics, 1966
- I. A possible new definition of electronegativityProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1951
- A resonating-valence-bond theory of metals and intermetallic compoundsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1949
- New regularities in vibrational spectraProceedings of the Physical Society, 1946
- The Nature of the Interatomic Forces in MetalsPhysical Review B, 1938