A ferryl(V) pathway in DNA cleavage induced by Fe II (haph) with O2 or H2O2
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 222-224
- https://doi.org/10.1039/c39920000222
Abstract
The mechanism of DNA cleavage induced by both FeII(haph)–O2 and FeIII(haph)–H2O2 is shown by the dimethyl sulfoxide scavenging procedure to occur via ferryl(V)intermediates.Keywords
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