Synthesis and X-ray crystal structure of a 1,1-dithiolate cluster compound containing a cube of eight AgIatoms, [AgI8{S2CC(CN)2}6]4–

Abstract
The novel [AgI 8{S2CC(CN)2}6]4– cluster compound contains a cube of Ag1 atoms (average AgI–AgI distance 3·02 Å) which is inscribed into an icosahedron of twelve S atoms so that each AgI atom is planar co-ordinated by a triangular arrangeement of three S atoms.

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