Macrocycle reorientation in solid 18-crown-6 complexes detected by 1H and 13C n.m.r. spectroscopy

1 January 1989

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 18,p. 1306-1308
https://doi.org/10.1039/c39890001306

Abstract

Solid state ¹H and ¹³C n.m.r. spectra of 18-crown-6 complexes indicate reorientational motions of the macrocyclic ether, at or near room temperature, in contrast with apparently static X-ray structures.

Keywords

STRUCTURES
MACROCYCLIC
REORIENTATIONAL
STATIC
SPECTRA
ETHER
ROOM
13C
N.M.R

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