Hydrogen-1 nuclear magnetic resonance evidence for trans addition in oxythallation of acyclic olefins
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 3,p. 234-237
- https://doi.org/10.1039/dt9780000234
Abstract
Hydrogen-1 n.m.r. conformational analyses of some stabilised oxythallation products from styrene, o-allylphenol propylene, and oct-1-ene have been performed primarily on the basis of the variation in thallium–proton spin–spin couplingconstants. The results have been applied to the oxythallated adduct of trans-β-deuteriostyrene to provide the first direct evidence for trans addition in the oxythallation of acyclic olefins.Keywords
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