Beiträge zur Chemie des Bors, XCVII Eine Untersuchung des Substituentenaustausches zwischen Trithiadiborolanen / Contributions to the Chemistry of Boron, XCVII An Investigation of the Substituent Exchange between Trithiadiborolanes
Open Access
- 1 February 1979
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 34 (2) , 135-139
- https://doi.org/10.1515/znb-1979-0202
Abstract
The substituent exchange between trithiadiborolanes has been studied by the 10B isotope technique. A simultaneous exchange of the substituent and the boron atom to which the substituent is bound was observed. This result is explained by a mechanism comprising a conformationally flexible ten membered ring as an intermediate. The exchange occurs not only between differently substituted trithiadiborolanes but also between trithiadiborolanes of one sort.Keywords
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