Stereochemical control of cis- and trans-TiCl2 groups in six-coordinate complexes [(L)TiCl2] (L2− = N2O2-donor Schiff base) and reactions with trimethylaluminium to form cationic aluminium species
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 4,p. 323-324
- https://doi.org/10.1039/a808372j
Abstract
The first example of a cis-configuration of the TiCl2 group in a six-coordinate titanium complex [(L)TiCl2], involving a tetradentate N2O2-donor Schiff base ligand (L2–), is reported, and reactions of such complexes with trimethyl aluminium have been shown to generate cationic aluminium species.Keywords
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