A Synthetic Approach to Quassin. Introduction of Functionality and Stereochemistry by a Diels–Alder Reaction

15 February 1975

journal article
Published by Canadian Science Publishing in Canadian Journal of Chemistry

Vol. 53 (4) , 619-621
https://doi.org/10.1139/v75-087

Abstract

Using a Lewis acid catalyzed Diels–Alder reaction as the key step, the crystalline synthetic intermediate (17) has been prepared. Compound 17 contains all C-atoms of quassin (1) and stereochemistry and 0-functionality suitable for the conversion into 1.

Keywords

FUNCTIONALITY
CONVERSION
STEREOCHEMISTRY
INTRODUCTION
COMPOUND
STEP
LEWIS
CRYSTALLINE
SYNTHETIC APPROACH
QUASSIN

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