Chiral cyclohexanes from carbohydrates: successful carbocyclisation of a D-arabino-hex-5-enopyranoside derivative
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1268-1269
- https://doi.org/10.1039/c39840001268
Abstract
Carbocyclisation of a hex-5-enopyranoside of D-arabino configuration under modified Ferrier's conditions gave chiral substituted cyclohexanes, which are precursors of aminocyclitols and useful synthetic intermediates, in good yield and without side reactions.Keywords
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