MS/MS of energetic compounds. A collisional induced dissociation study of some polynttrobishcmocubanes
- 1 January 1986
- journal article
- research article
- Published by Taylor & Francis in Journal of Energetic Materials
- Vol. 4 (1-4) , 115-131
- https://doi.org/10.1080/07370658608011336
Abstract
A collisional induced dissociation (CID) study was done on 3,5,5-trinitropentacyclodecane and 5,5-dinitropentacyclodecane-3-carboxylic acid using tandem high-resolution MS/MS. Fragmentation pathways were determined in the El ionization mode. It was found that fragmentation of the C-N bonds–resulting in losses of the NO2groups–takes place before the fragmentation of the C-C bonds.Keywords
This publication has 10 references indexed in Scilit:
- Deuterium isotope effects in condensed-phase thermochemical decomposition reactions of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocineThe Journal of Physical Chemistry, 1985
- Mass spectral fragmentation pathways in 2,4,6-trinitrotoluene derived from a MS/MS unimolecular and collisionally activated dissociation studyJournal of Mass Spectrometry, 1984
- Synthesis of 3,5,5-trinitropentacyclo[5.3.0.02,6.03,10.04,8]decaneThe Journal of Organic Chemistry, 1984
- Initiation mechanism of TNT: Deuterium isotope effect as an experimental probeJournal of Energetic Materials, 1983
- Mass spectrometry of explosives: Nitro compounds, nitrate esters, and nitraminesMass Spectrometry Reviews, 1982
- Mass spectral fragmentation pathways in RDX and HMX. A mass analyzed ion kinetic energy spectrometric/collisional induced dissociation studyJournal of Mass Spectrometry, 1982
- Application of mass-analysed ion kinetic energy spectrometry (MIKES) to the determination of the structures of unknown compoundsThe Analyst, 1978
- Deuterium isotope effects in the thermochemical decomposition of liquid 2,4,6-trinitrotoluene: application to mechanistic studies using isothermal differential scanning calorimetry analysisThe Journal of Organic Chemistry, 1977
- Metastable ion characteristics. XXII. Collisional activation spectra of organic ionsJournal of the American Chemical Society, 1973
- Electron‐impact fragmentation of some secondary aliphatic nitramines. Migration of the nitro group in heterocyclic nitraminesJournal of Mass Spectrometry, 1970