Aromatic Polyhedral Hydroxyborates: Bridging Boron Oxides and Boron Hydrides
- 14 April 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (8) , 1061-1064
- https://doi.org/10.1002/(sici)1521-3773(19990419)38:8<1061::aid-anie1061>3.0.co;2-b
Abstract
No explosion, but per-B-hydroxylation occurs if the icosahedral boron hydrides [closo-B12H12]2− (see picture), [closo-CB11H12]−, or closo-1,12-(CH2OH)2-1,12-C2B10H10 are refluxed in 30 % hydrogen peroxide. Thus, the three isoelectronic species [closo-B12(OH)12]2−, [closo-1-H-1-CB11(OH)11]−, and closo-1,12-H2-1,12-C2B10(OH)10 were obtained. ○=BH, ○=BOH.Keywords
This publication has 0 references indexed in Scilit: