Sublimation of Aluminum Oxide in Hydrogen

Publisher Website
Google Scholar
Abstract
The sublimation of single‐crystal Al2O3spheres and plates in pure, dry H2was studied. The kinetics of this process are controlled by diffusion of the volatile gaseous products through the stagnant gas boundary layer adjacent to the surface. The evaporating species are probably the lower oxides of aluminum obtained by reduction of Al2O3with hydrogen. The etching of the surface by heating in dry H2was also studied. The basal planes developed most easily. The facets formed were fine steps consisting of basal and prismatic planes. Condensation of the vapors in the form of small crystallites of thin plates and whiskers of Al2O3was observed in the colder regions of the furnace.

This publication has 7 references indexed in Scilit: