Trimethylsilylmethyl Ketones in Synthesis A Regiospecific Synthesis of ?, ?-Unsaturated Esters, Amides and Nitriles
- 1 January 1975
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 5 (1) , 15-19
- https://doi.org/10.1080/00397917508063509
Abstract
In connection with our studies directed toward a new procedure for the preparation of unsaturated butyrolactones, a method for introduction of unsaturation β,γ to an ester was required. This note reports our efforts in this area and extends the results obtained to other systems as well.Keywords
This publication has 6 references indexed in Scilit:
- Stereospecific synthesis of cis or trans olefins from β-ketosilanesTetrahedron Letters, 1974
- Isolation and characterization of lithio tert-butyl acetate, a stable ester enolateJournal of the American Chemical Society, 1973
- Ionization of an .alpha.-hydrogen of acetonitrile by n-butyllithium and alkali amides. Condensations with ketones and aldehydes to form .beta.-hydroxynitrilesThe Journal of Organic Chemistry, 1968
- Erzeugung und Reaktionen von α‐Li‐N.N‐Dimethyl‐acetamid und ‐propionamid und von α‐Li‐AcetonitrilEuropean Journal of Inorganic Chemistry, 1968
- Preparation and Reactions of α-Halo Derivatives of Certain Tetra-substituted Hydrocarbon Silanes. Grignard Syntheses of Some Silyl Compounds1Journal of the American Chemical Society, 1952
- II. Derivatives of 2,6-Diaminopyridine1Journal of the American Chemical Society, 1947