Intensities of Vibrational and Rotational Spectra of Charged Diatomic Molecules
- 15 January 1962
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 36 (2) , 478-480
- https://doi.org/10.1063/1.1732535
Abstract
It is shown that there exists a contribution to the transition moment (and hence to the spectral intensity) associated with pure rotational and with vibration-rotational transitions which is proportional to the net charge residing on the molecule and to the difference in masses of the nuclei. Hence, molecule-ions such as HD+ and (Cl35Cl37)+ should absorb and emit dipole radiation with significant intensity in the vibrational and rotational spectral regions.Keywords
This publication has 4 references indexed in Scilit:
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- Quantitative Infrared Intensity Measurements. I. Carbon Monoxide Pressurized with Infrared-Inactive GasesThe Journal of Chemical Physics, 1951
- The Vibration-Rotation Energies of MoleculesReviews of Modern Physics, 1951