Transition metal–carbon bonds. Part XIII. Di-µ-chlorodicarbonyldi-(ethylene)dirhodium(I)
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 211-212
- https://doi.org/10.1039/j19680000211
Abstract
[Rh2Cl2(CO)4] and [Rh2Cl2(C2H4)4] react in benzene solution to give [Rh2Cl2(CO)2(C2H4)2] in good yield. [Rh2Cl2(CO)2(C2H4)2] reacts with hydrogen chloride to given an ethylrhodium(III) complex [RhCl2Et(CO)]x which in turn reacts with dimethylphenylphosphine to give [RhCl2Et(CO)(PMe2Ph)2]. Nuclear magnetic resonance and infrared data are given.Keywords
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