Enantio- and Regioselective Heck-Type Reaction of Arylboronic Acids with 2,3-Dihydrofuran
- 10 April 2007
- journal article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 72 (10) , 3875-3879
- https://doi.org/10.1021/jo070170v
Abstract
Reported herein is a protocol for the enantioselective Pd(II)-catalyzed Heck-type reaction between arylboronic acids and 2,3-dihydrofuran. The highest chemical and optical yields were obtained when a Pd(OAc)2/(R)-MeO(biphenylphosphine) or a Pd(OAc)2/(R)-(2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) catalyst and a Cu(OAc)2 reoxidant were employed.Keywords
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