Asymmetric synthesis of a seven carbon anit-3,5-diol building block. A polyacetate derivative with completely resolved C 2 symmetry

Abstract
Methyl (3R,5R)-5-benzyloxy-7-([1,3]dithian-2-yl)-3-hydroxyheptanoate (+)-7 has been prepared from 8-oxabicyclo[3.2.1]oct-6-en-3-one 1 in 7 steps and 40% overall yield.

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