The palladium(II) coordination chemistry of ferrocenylphosphinobipyridines: a novel trans-chelating ligand system
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 459-460
- https://doi.org/10.1039/c39950000459
Abstract
The reaction of dichloro(cycloocta-1,5-diene)palladium(II) with l-dipheny (L1) or 1-phenyl(n-butyl)-phosphino-1′-[6-(2,2′-bipyridyl)]ferrocene (L2) results in the novel trans-coordination geometry with the β-pyridinyl ring and the phosphine group binding to the metal centre, as proved by a crystal structure determination of [PdCl2L1][PdCl2(cod)].Keywords
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