Charge transfer in mixed-valence solids. Part I. Crystal spectra of chlorocuprates(I,II)
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1045-1046
- https://doi.org/10.1039/j19670001045
Abstract
The intensity of the mixed-valence absorption in a series of mixed-valence chlorocuprates has been measured as a function of the mole fraction of copper(I). The low intensity of the band agrees with its assignment as an intermolecular charge transfer from a chlorocuprate(I) anion to a chlorocuprate(II).Keywords
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