Adducts of the halogenosilanes. Part II. Physical properties and structures

1 January 1967

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 705-712
https://doi.org/10.1039/j19670000705

Abstract

The infrared spectra of adducts of the halogenosilanes SiH_nX_4–n(n= 0, 1, 2, or 3; X = F, Cl, Br, or I) with pyridine trimethylamine, and tetramethylethylenediamine are reported, and are used in conjunction with measurements of conductivity to deduce that the adducts of the bromo- and iodo-silanes are probably ionic, whilst those of the fluorosilanes are probably molecular or macromolecular. The n.m.r. and u.v. spectra of some of these adducts are also given.

Keywords

PHYSICAL PROPERTIES

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