Zur Reaktion aromatischer Phosphanderivate mit Elektronen, I. / On the Reaction of Aromatic Phosphane Derivatives with Electrons, I.
Open Access
- 1 February 1981
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 36 (2) , 150-156
- https://doi.org/10.1515/znb-1981-0207
Abstract
The compounds ;p-Me2P(X)-C6H4-P(X)Me2, X = O, S, Se, NPh undergo one-electron reduction at a mercury cathode or on reaction with solvated electrons in a K/18-crown-6/THF mixture. The radical anions formed are persistent and have been characterized by ESR. They may be described as complexes of the spin-bearing moiety p-Me2P-C6H4-PMe2 · with the coordinated groups X.Keywords
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