Competitive chlorination reactions with ICl. II. CH4, C2H6, C3H8, and C2H5Cl

Abstract
The H atom abstraction from CH4, C2H6, C3H8, and C2H5Cl by Cl atoms produced by photolysis of ICl in daylight has been studied. Relative rates for the abstractions from CH4, C2H6, primary and secondary hydrogens from propane, and for the abstraction from the CH3 and CH2Cl sides of C2H5Cl have been obtained at room temperature. These data are compared with other literature values.

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