Peroxides of elements other than carbon. Part XVII. Reaction of tri-2-norbornylboranes with neutral hydrogen peroxide
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 1815-1818
- https://doi.org/10.1039/j29700001815
Abstract
The reaction between three epimeric tri-2-norbornylboranes and neutral 30% aqueous hydrogen peroxide at 25° has been investigated in the absence and presence of iodine and of carbon tetrachloride. Whereas norbornane, 2,2′-binorbornane, norbornyl iodide, and norbornyl chloride are produced through an intermediate norbornyl radical, the configuration of the norbornanol which is isolated suggests that it is formed largely by a polar process.Keywords
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