New Synthesis of Phosphorous and Phosphoric Acid Esters

1 January 1991

journal article
research article
Published by Georg Thieme Verlag KG in Synthesis

Vol. 1991 (03) , 201-204
https://doi.org/10.1055/s-1991-26418

Abstract

Reaction of alcohols with dialkyl phosphites in the presence of titanium tetraalkoxides results in a displacement of both or one ester function(s) by the RO groups of the alcohol used. The mixed phosphites, (R³O)(R¹O)P(O)H, prepared by this method can be used as substrates for the mixed phosphates, (R⁴O)(R³O)(R¹O)PO.

Keywords

PHOSPHOROUS
FUNCTION
ALCOHOL
ESTER
SUBSTRATES
TITANIUM
DIALKYL
PHOSPHATES
TETRAALKOXIDES

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