Hybrid open frameworks (MIL-n). Part 6 Hydrothermal synthesis and X-ray powder ab initio structure determination of MIL-11, a series of lanthanide organodiphosphonates with three-dimensional networks, LnIIIH[O3P(CH2)nPO3] (n=1-3)
- 1 January 1998
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 8 (12) , 2749-2755
- https://doi.org/10.1039/a802715c
Abstract
A series of lanthanide and yttrium propylenediphosphonates has been prepared hydrothermally (210°C, 4 days) by action of propylenediphosphonic acid on the metal chlorides. The crystal structure of the gadolinium compound GdIIIH[O3P(CH2)3PO3] has been determined ab initio from X-ray powder diffraction data and refinKeywords
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