High-Order Time-Dependent Perturbation Theory for Classical Mechanics and for Other Systems of First-Order Ordinary Differential Equations
- 1 May 1970
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 52 (9) , 4803-4807
- https://doi.org/10.1063/1.1673715
Abstract
A time‐dependent perturbation solution is derived for a system of first‐order nonlinear or linear ordinary differential equations. By means of an ansatz, justified a posteriori, the latter equations can be converted to an operator equation which is solvable by several methods. The solution is subsequently specialized to the case of classical mechanics. For the particular case of autonomous equations the solution reduces to a well‐known one in the literature. However, when collision phenomena are treated and described in a classical “interaction representation” the differential equations are typically nonautonomous, and the more general solution is required. The perturbation expression is related to a quantum mechanical one and will be applied subsequently to semiclassical and classical treatments of collisions.Keywords
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