Hydrolytic studies on (η5-C5Me5)TiMe3; X-ray structure of [(η5-C5Me5)TiMe(µ-O)]3containing a Ti3O3ring

Abstract
Successive hydrolysis of (η5-C5Me5)TiMe3(2) gives first [(η5-C5Me5)TiMe2]2(µ-O)(3) and then [(η5-C5Me5)TiMe(µ-O)]3(4); the crystal structure of (4) reveals a Ti3O3 ring.

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