Solvent effects on discrimination in the dissociative substitution of pentacyano(ligand)ferrate(II) comptexes in alcohol–water mixtures
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 3,p. 244-247
- https://doi.org/10.1039/dt9780000244
Abstract
Solvent effects on the discriminatory properties of the transient [Fe(CN)5]3– intermediate in the dissociative (D) substitution at the complex ions [Fe(CN)5L]3–(L = 3- or 4-cyanopyridine) are described. The solvents employed are methanol—, ethanol—, and t-butyl alcohol–water mixtures; in each case the incoming group is cyanide ion.Keywords
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