Generation of unnatural α,α-disubstituted amino acid derivatives from cyclic sulfamidates
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 11,p. 1421-1430
- https://doi.org/10.1039/a901667h
Abstract
Cyclic sulfamidates function as excellent precursors to a variety of unnatural α,α-disubstituted amino acid derivatives by ring opening with a suitable nucleophile. Addition of various nucleophiles to a sulfamidate derived from 2-methylserine is described.Keywords
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