Versatile Reactivity of the Bis(dihydrogen) Complex RuH2(H2)2(PCy3)2 toward Functionalized Olefins: Olefin Coordination versus Hydrogen Transfer via the Stepwise Dehydrogenation of the Phosphine Ligand
- 5 March 1996
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 15 (5) , 1427-1434
- https://doi.org/10.1021/om950888d
Abstract
No abstract availableThis publication has 23 references indexed in Scilit:
- Synthesis and Reactivity of Hydridotris(pyrazolyl) Borate Dihydrogen Ruthenium ComplexesJournal of the American Chemical Society, 1995
- Highly Selective Dehydrogenative Silylation of Ethylene Using the Bis(dihydrogen) Complex RuH2(H2)2(PCy3)2 as Catalyst PrecursorOrganometallics, 1995
- Synthesis of Cyclopentadienyl(1,4-diisopropyl-1,3-diazabutadiene)(L)ruthenium Trifluoromethanesulfonate (L = Alkene, Alkyne, CO, Pyridine, PPh3). X-ray Structure of [(.eta.5-C5H5)Ru(iPr-DAB)(.eta.2-propene)][CF3SO3]Organometallics, 1994
- Alkene complexes of ruthenium(0): crystal structures, isomerism and fluxionalityJ. Chem. Soc., Dalton Trans., 1994
- Coordination chemistry of dihydrogenChemical Reviews, 1993
- Dehydrogenation of a cyclohexyl group in tricyclohexylphosphine complexes of ruthenium. X-ray crystal structure of [Ru(C6H9PCy2)(CF3COO)]2(.mu.-CF3COO)2(.mu.-OH2)Organometallics, 1991
- Reactivity of ruthenium trihydrides with Broensted and Lewis acids. X-ray crystal structures of {Cp*Ru[C6H9P(C6H11)2]}BF4 and {{Cp*RuH[P(C6H11)3]}(.mu.-H)2Cu(.mu.-Cl)}2. Evidence for exchange coupling between two hydrogen atomsOrganometallics, 1991
- Synthesis and reactivity of halide, hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)(bisphosphine)iron(II)Organometallics, 1990
- A stable .eta.2-dihydrogen complex of cobalt. Role of the hydrogen-hydrogen interaction in hydrogen transfer from metal to alkeneJournal of the American Chemical Society, 1988
- Preparation of polyhydride complexes of ruthenium by direct hydrogenation of zerovalent olefinic derivatives. Mononuclear complexes of the type RuH6L2 and RuH4L3. Spontaneous hydrogen-deuterium exchange between the phosphine protons and the solvent catalyzed by RuH4L3Organometallics, 1985