Syntheses and crystallographic characterizations of trinuclear (µ3-O) zirconium complexes
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 823-824
- https://doi.org/10.1039/c39950000823
Abstract
The new trinuclear complex [{(η5-C5H5)2ZrO}3(µ3-O)]5 shows unexpected interatomic distances and angles and a planar µ3-O, while the related trinuclear zirconium cation cluster [{(C5H5)Zr}3(µ3-O)(µ-OH)3(µ2-HCO2)3]Cl· HCONMe2·0.5H2O 7 exhibits a pyramidal µ3-O.Keywords
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