Synthesis of 24-methyl sterols stereospecifically labelled with 2H in the isopropyl methyl groups. 13C NMR spectral assignment of C-26 and C-27 resonances
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 263-264
- https://doi.org/10.1039/c39900000263
Abstract
Through analysis of the 13C NMR spectra of (25S)-[27-2H]campesterol (1) and (25R)-[26-2H]dihydrobrassicasterol (2), the C-26 and C-27 resonances have been unambiguously assigned; the biosynthetic applications are discussed.Keywords
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