The Phase Diagram of the Pb–Mo–S System at 1250 K and Some Properties of the Superconducting PbMo6S8
- 1 January 1981
- journal article
- research article
- Published by Wiley in Crystal Research and Technology
- Vol. 16 (7) , 777-784
- https://doi.org/10.1002/crat.2170160708
Abstract
PbxMo6Sy arises as the sole ternary compound in the System Pb–Mo–S. At 1250 K it is surrounded by 4 phase regions with 3 solid phases. It has a homogeneity range of between 0.9 ≤ x < 1.1 and 7.6 ≤ y > ≤ 7.9. Tc changes within the homogeneity range. Chemical transport is possible within a limited section of the phase diagram in the presence of lead halides.Keywords
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